Friday, October 23, 2009

Chemical and physical properties


Water is the chemical substance with chemical formula H2O: one molecule of water has two hydrogen atoms covalently bonded to a single oxygen atom.

Water appears in nature in all three common states of matter and may take many different forms on Earth: water vapor and clouds in the sky; seawater and icebergs in the polar oceans; glaciers and rivers in the mountains; and the liquid in aquifers in the ground.

The major chemical and physical properties of water are:

* Water is a tasteless, odorless liquid at standard temperature and pressure. The color of water and ice is, intrinsically, a very light blue hue, although water appears colorless in small quantities. Ice also appears colorless, and water vapor is essentially invisible as a gas.[9]

* Water is transparent, and thus aquatic plants can live within the water because sunlight can reach them. Only strong UV light is slightly absorbed.

* Since the water molecule is not linear and the oxygen atom has a higher electronegativity than hydrogen atoms, it carries a slight negative charge, whereas the hydrogen atoms are slightly positive. As a result, water is a polar molecule with an electrical dipole moment. The net interactions between the dipoles on each molecule cause an effective skin effect at the interface of water with other substances, or air at the surface, the latter given rise to water's high surface tension. This dipolar nature contributes to water molecules' tendency to form hydrogen bonds which cause water's many special properties.[10] The polar nature also favors adhesion to other materials.

* A result of interplay of these properties, Capillary action refers to the tendency of water to move up a narrow tube against the force of gravity. This property is relied upon by all vascular plants, such as trees.

* Water is a good solvent and is often referred to as the universal solvent. Substances that dissolve in water, e.g., salts, sugars, acids, alkalis, and some gases – especially oxygen, carbon dioxide (carbonation) are known as hydrophilic (water-loving) substances, while those that do not mix well with water (e.g., fats and oils), are known as hydrophobic (water-fearing) substances.

* All the major components in cells (proteins, DNA and polysaccharides) are also dissolved in water.

* Pure water has a low electrical conductivity, but this increases significantly with the dissolution of a small amount of ionic material such as sodium chloride.

* The boiling point of water (and all other liquids) is dependent on the barometric pressure. For example, on the top of Mt. Everest water boils at about 68 °C (154 °F), compared to 100 °C (212 °F) at sea level. Conversely, water deep in the ocean near geothermal vents can reach temperatures of hundreds of degrees and remain liquid.

* Water has the second highest specific heat capacity of any known substance, after ammonia, as well as a high heat of vaporization (40.65 kJ·mol−1), both of which are a result of the extensive hydrogen bonding between its molecules. These two unusual properties allow water to moderate Earth's climate by buffering large fluctuations in temperature.

* The maximum density of water occurs at 3.98 °C (39.16 °F).[11] Water becomes even less dense upon freezing, expanding 9%. This results in an unusual phenomenon: water's solid form, ice, floats upon water, allowing organisms to survive inside a partially-frozen water body because the water on the bottom has a temperature of around 4 °C (39 °F).

ADR label for transporting goods dangerously reactive with water

* Water is miscible with many liquids, for example ethanol, in all proportions, forming a single homogeneous liquid. On the other hand, water and most oils are immiscible usually forming layers according to increasing density from the top. As a gas, water vapor is completely miscible with air.

* Water forms an azeotrope with many other solvents.

* Water can be split by electrolysis into hydrogen and oxygen.

* As an oxide of hydrogen, water is formed when hydrogen or hydrogen-containing compounds burn or react with oxygen or oxygen-containing compounds. Water is not a fuel, it is an end-product of the combustion of hydrogen. The energy required to split water into hydrogen and oxygen by electrolysis or any other means is greater than the energy released when the hydrogen and oxygen recombine.[12]

* Elements which are more electropositive than hydrogen such as lithium, sodium, calcium, potassium and caesium displace hydrogen from water, forming hydroxides. Being a flammable gas, the hydrogen given off is dangerous and the reaction of water with the more electropositive of these elements may be violently explosive.

* At ultrahigh pressures found in deep interiors of giant planets Uranus and Neptune water may become metallic, which would have important implications for the generation of the magnetic fields of these planets.

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